Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of p-Quinone Methides-Reference-Cited by-同舟云学术

Preparation of Chitosan-Composite-Film-Supported Copper Nanoparticles and Their Application in 1,6-Hydroboration Reactions of p-Quinone Methides

Published:2022-11-17 Issue:22 Volume:27 Page:7962
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Chen Shuhan¹²,Wen Wei¹²,Zhao Xue¹²,Zhang Zelang¹²,Li Weishuang¹,Zhang Yaoyao¹,Li Bojie¹,Zhu Lei¹²

Affiliation:

1. School of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, China

2. School of Materials Science and Engineering, Hubei University, Wuhan 430062, China

Abstract

Here, we describe the preparation of copper nanoparticles that are stabilized on a chitosan composite film (CP@Cu). This material could catalyze the 1,6-hydroboration reactions of p-quinone methides with B2pin2 as a boron source under mild conditions. This reaction exhibited very good functional group compatibility, and the organoboron compounds that were formed could easily be converted into corresponding hydroxyl products with good to excellent yields. This newly developed methodology provides an efficient and sequential pathway for the synthesis of gem-disubstituted methanols.

Funder

National Natural Science Foundation of China

Hubei University Excellent Young and Middle-aged Science and Technology Innovation Team Project

Opening Fund of Hubei Key Laboratory of Processing and Application of Catalytic materials, and Huanggang Normal University

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/27/22/7962/pdf

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