3D SERS Substrate of Z-Shaped Ag Nanorod Array for Thiabendazole Detection

Author:

Zhang Yongjun12,Zhao Xiaoyu1,Mao Deyuan1,Wen Jiahong23,Gao Renxian4,Wang Yaxin1

Affiliation:

1. School of Material and Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, China

2. Shangyu Institute of Science and Engineering, Hangzhou Dianzi University, Shaoxing 312000, China

3. The College of Electronics and Information, Hangzhou Dianzi University, Hangzhou 310018, China

4. Department of Physics, Xiamen University, Xiamen 361005, China

Abstract

Ag nanoparticles sputtered on silicon wafer are used as masks for the fabrication of silicon columns by ion etching, which induces the growth of the inclined Ag nanorod by inclined Ag sputtering. V-shaped and Z-shaped Ag nanorods can be obtained by varying incline angles and deposition times. SERS detection and FDTD simulation are used to compare and investigate the enhanced electromagnetic coupling of incline nanorod arrays with different shapes in three-dimensional space, which indicates that Z-shaped nanorods show good SERS properties. The Z-shaped Ag nanorod array is used as a SERS substrate for the detection of thiabendazole with a concentration down to 10−11 M.

Funder

National Natural Science Foundation of China

National Natural Science Foundation of Zhejiang Province

Fundamental Research Funds for the Provincial Universities of Zhejiang

Key Research Project of Zhejiang Lab

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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