Novel Microwave-Assisted Synthesis of COFs: 2020–2022

Author:

Rodríguez-Carríllo Cristina1,Benítez Miriam1,El Haskouri Jamal2ORCID,Amorós Pedro2ORCID,Ros-Lis Jose V.1ORCID

Affiliation:

1. REDOLI Research Group, Instituto Interuniversitario de Investigación de Reconocimiento Moleculary Desarrollo Tecnológico (IDM), Universitat Politècnica de València, Universitat de València, Doctor Moliner 50, 46100 Valencia, Spain

2. Institut de Ciència dels Materials (ICMUV), Universitat de València, P.O. Box 22085, 46071 Valencia, Spain

Abstract

Covalent organic frameworks (COFs) have emerged as a new type of crystalline porous polymers of great interest. However, their preparation requires long reaction times. Microwave-assisted synthesis (MAS) offers an interesting approach to increasing the reaction rate of chemical processes. Thus, microwaves can be a key tool for the fast and scalable synthesis of COFs. Since our previous review on the topic, the preparation of COFs with microwaves has been evolving. Herein, we present a compilation of COFs studies and experiments published in the last three years on the synthesis of COFs using microwave-assisted synthesis as a source of energy. The articles include imine, triazine, and other 2D COFs synthesized using MAS. The 3D COFs have also been compiled. The chemical structure of the monomers and the COFs and their main parameters of synthesis and application are summarized for each article.

Funder

Ministerio de ciencia e innovación

Generalitat Valenciana

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Reference69 articles.

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