High-Efficiency Oxygen Reduction Reaction Revived from Walnut Shell

Abstract

The development of inexpensive and efficient electrocatalysts for oxygen reduction reactions (ORR) remains a challenge with respect to renewable energy technologies. In this research, a porous, nitrogen-doped ORR catalyst is prepared using the hydrothermal method and pyrolysis with walnut shell as a biomass precursor and urea as a nitrogen source. Unlike past research, in this study, urea is not directly doped; instead, a new type of doping is carried out after annealing at 550 °C. In addition, the sample’s morphology and structure are analyzed and characterized by scanning electron microscopy (SEM) and X-ray powder diffraction (XRD). A CHI 760E electrochemical workstation is used to test NSCL-900’s performance in terms of oxygen reduction electrocatalysis (ORR). It has been found that the catalytic performance of NSCL-900 is significantly improved compared with that of NS-900 without urea doping. In a 0.1 mol/L KOH electrolyte, the half-wave potential can reach 0.86 V (vs. RHE) and the initial potential is 1.00 V (vs. RHE). The catalytic process is close to four-electron transfer and there are large quantities of pyridine nitrogen and pyrrole nitrogen.