Flammability of Thick but Thermally Thin Materials including Bio-Based Materials

Author:

Sonnier Rodolphe1ORCID,Dumazert Loïc1,Regazzi Arnaud2,Deborde Lily3ORCID,Lanos Christophe3

Affiliation:

1. Polymers Composites and Hybrids (PCH), IMT Mines Ales, 30319 Ales, France

2. LMGC, IMT Mines Ales, University Montpellier, CNRS, 30100 Ales, France

3. Laboratoire de Génie Civil et Génie Mécanique, University Rennes, 3 rue du Clos Courtel, 35704 Rennes, France

Abstract

The fire reaction of various types of flammable lightweight materials is investigated using a cone calorimeter. The influences of parameters such as sample density, sample mass, effective heat of combustion and heat flux on the mass loss after exposition are discussed. Interpretations of the hemp fibers’ tests results lead us to propose a phenomenological model able to calculate the peak of heat release rate (pHRR) of such thermally thin materials, with or without flame retardant. A database gathering the whole results of tests performed on a large set of materials including fibers, bio-resources panels, bio-based concretes and fabrics is used to validate the proposed model. Interestingly, the model is found to be relevant also for denser wood specimens. The model is based on the distinction of the contributions of the exposed top layer and the deeper layer to the combustion. Indeed, in such materials, the heat conduction is limited (either by the intrinsic properties of the material or by the formation of an insulating char) and therefore the pHRR only depends on a limited volume of materials directly absorbing the heat flux from the radiant cone. Accuracy and limitations of the model are discussed.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Reference30 articles.

1. Karibati (2019, February 27). Intérêts & Potentiels [WWW Document]. Available online: http://www.karibati.fr/materiaux-biosources/interets-potentiels/.

2. Ségalen, A. (2005). Le Chanvre en France, Editions du Rouergue.

3. Amziane, S., and Collet, F. (2017). Bio-Aggregates Based Building Materials: State-of-the-Art Report of the RILEM Technical Committee 236-BBM, Springer.

4. Cérézo, V. (2005). Propriétés Mécaniques, Thermiques et Acoustiques d’un Matériau à base de Particules Végétales: Approche Expérimentale et Modélisation Théorique, Institut National des Sciences Appliquées de Lyon.

5. Collet, F. (2004). Caractérisation Hydrique et Thermique de Matériaux de Génie Civil à Faibles Impacts Environnementaux, Institut National des Sciences Appliquées de Rennes.

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