Evaluation the Potential of Onion/Laponite Composites Films for Sustainable Food Packaging with Enhanced UV Protection and Antioxidant Capacity

Author:

Barbosa Maciel L.1ORCID,Oliveira Leticia M. de2ORCID,Paiva Robert1ORCID,Dametto Alessandra C.3,Dias Diogenes dos S.3,Ribeiro Clovis A.4ORCID,Wrona Magdalena5ORCID,Nerín Cristina5ORCID,Barud Hernane da S.6ORCID,Cruz Sandra A.1ORCID

Affiliation:

1. Department of Chemistry, Federal University of São Carlos (UFSCar), São Carlos 13565-905, Brazil

2. Department of Physics, Federal University of the São Francisco Valley (UNIVASF), Petrolina 56300-000, Brazil

3. BioSmart Nanotechnology Ltda., Araraquara 14808-162, Brazil

4. Institute of Chemistry, São Paulo State University (UNESP), Araraquara 14800-900, Brazil

5. Engineering Research Institute of Aragon (I3A), University of Zaragoza, María de Luna 3, 50018 Zaragoza, Spain

6. Laboratory of Biopolymers and Biomaterials (BIOPOLMAT), University of Araraquara (UNIARA), Araraquara 14801-320, Brazil

Abstract

Agro-industrial residues have attracted attention for their applications in the field of biodegradable packaging. Recently, our research group has developed onion-based films with promising properties for this type of application due to their non-toxicity, biocompatibility and biodegradability. Therefore, in this study, we investigated the effect of Laponite clay concentration on the physicochemical and antioxidant properties of the onion-based films, which were prepared by a casting method. The XRD and FTIR data confirm the presence of the mineral clay in the onion-based films. These findings are consistent with those obtained from FE-SEM analysis, which revealed the presence of typical Laponite grains. In terms of wettability, the results show that the clay decreases the hydrophilic character of the material but slightly increases the water vapor permeation. Optical characterization revealed that the materials exhibited zero transmittance in the UV region and increased opacity in the visible region for composites containing 5% and 10% Laponite. Furthermore, the antioxidant test demonstrated higher antioxidant potential in the composites compared to the pure films. Consequently, these results suggest that the formation of Laponite and onion composites could be an essential strategy for developing natural polymers in the field of food contact packaging.

Funder

São Paulo State Research Foundation

National Council for Scientific and Technological Development

HSB

INCT-INFO, FAPESP

Ministry of Science and Innovation

Government of Aragon

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Reference47 articles.

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3. Onion and garlic polysaccharides: A review on extraction, characterization, bioactivity, and modifications;Kumari;Int. J. Biol. Macromol.,2022

4. Strategies for the Structural Analysis of Carbohydrates;Kamerling;Compr. Glycosci.,2007

5. Evaluation of Carbohydrates in Pukekohe Longkeeper and Grano Cultivars of Allium cepa;Somerfield;J. Agric. Food Chem.,2005

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