Fabrication Methods of Continuous Pure Metal–Organic Framework Membranes and Films: A Review

Author:

Xing Qinglei12,Xu Xiangyou12,Li Haoqian12,Cui Zheng12,Chu Binrui12,Xie Nihao12,Wang Ziying23,Bai Peng13ORCID,Guo Xianghai45ORCID,Lyu Jiafei12

Affiliation:

1. Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

2. Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin University, Tianjin 300350, China

3. Department of Catalytic Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China

4. Tianjin Key Laboratory for Marine Environmental Research and Service, School of Marine Science and Technology, Tianjin University, Tianjin 300072, China

5. Key Laboratory of Ocean Observation Technology of Ministry of Natural Resources, School of Marine Science and Technology, Tianjin University, Tianjin 300072, China

Abstract

Metal–organic frameworks (MOFs) have drawn intensive attention as a class of highly porous, crystalline materials with significant potential in various applications due to their tunable porosity, large internal surface areas, and high crystallinity. This paper comprehensively reviews the fabrication methods of pure MOF membranes and films, including in situ solvothermal synthesis, secondary growth, electrochemical deposition, counter diffusion growth, liquid phase epitaxy and solvent-free synthesis in the category of different MOF families with specific metal species, including Zn-based, Cu-based, Zr-based, Al-based, Ni-based, and Ti-based MOFs.

Funder

National Natural Science Foundation of China

Tianjin Research Innovation Project for Postgraduate Students

Publisher

MDPI AG

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