A New Route of Valorization of Petrochemical Wastewater: Recovery of 1,3,5-Tris (4-tert-butyl-3-hydroxy-2,6-dimethyl benzyl)–1,3,5-triazine-2,4,6-(1H,3H,5H)-trione (Cyanox 1790) and Its Subsequent Application in a PP Matrix to Improve Its Thermal Stability

Author:

Hernández-Fernández Joaquín123ORCID,Ortega-Toro Rodrigo4,López-Martinez Juan5ORCID

Affiliation:

1. Chemistry Program, Department of Natural and Exact Sciences, San Pablo Campus, University of Cartagena, Cartagena 130015, Colombia

2. Chemical Engineering Program, School of Engineering, Universidad Tecnológica de Bolivar, Parque Industrial y Tecnológico Carlos Vélez Pombo, Km 1 Vía Turbaco, Turbaco 130001, Colombia

3. Department of Natural and Exact Science, Universidad de la Costa, Barranquilla 30300, Colombia

4. Food Packaging and Shelf-Life Research Group (FP&SL), Food Engineering Department, Universidad de Cartagena, Cartagena de Indias 130015, Colombia

5. Institute of Materials Technology (ITM), Universitat Politecnica de Valencia (UPV), Plaza Ferrandiz and Carbonell s/n, 03801 Alcoy, Spain

Abstract

The various chemicals in industrial wastewater can be beneficial for improving its circularity. If extraction methods are used to capture valuable components from the wastewater and then recirculate them throughout the process, the potential of the wastewater can be fully exploited. In this study, wastewater produced after the polypropylene deodorization process was evaluated. These waters remove the remains of the additives used to create the resin. With this recovery, contamination of the water bodies is avoided, and the polymer production process becomes more circular. The phenolic component was recovered by solid-phase extraction and HPLC, with a recovery rate of over 95%. FTIR and DSC were used to evaluate the purity of the extracted compound. After the phenolic compound was applied to the resin and its thermal stability was analyzed via TGA, the compound’s efficacy was finally determined. The results showed that the recovered additive improves the thermal qualities of the material.

Funder

Ministry of Science, Innovation, and Universities

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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