Catalytic System for Cross-Coupling of Heteroaryl Iodides with a Nitronyl Nitroxide Gold Derivative at Room Temperature-Reference-Cited by-同舟云学术

Catalytic System for Cross-Coupling of Heteroaryl Iodides with a Nitronyl Nitroxide Gold Derivative at Room Temperature

Published:2023-11-19 Issue:22 Volume:28 Page:7661
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Zayakin Igor¹,Romanenko Galina²^ORCID,Bagryanskaya Irina³,Ugrak Bogdan¹,Fedin Matvey²^ORCID,Tretyakov Evgeny¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Leninsky Ave. 47, Moscow 119991, Russia

2. International Tomography Center, Institutskaya Str. 3a, Novosibirsk 630090, Russia

3. N. N. Vorozhtsov Institute of Organic Chemistry, 9 Ac. Lavrentiev Avenue, Novosibirsk 630090, Russia

Abstract

A simple and highly effective methodology for the cross-coupling of heteroaryl iodides with NN–AuPPh3 at room temperature is reported. The protocol is based on a novel catalytic system consisting of Pd2(dba)3·CHCl3 and the phosphine ligand MeCgPPh having an adamantane-like framework. The present protocol was found to be well compatible with various heteroaryl iodides, thus opening new horizons in directed synthesis of functionalized nitronyl nitroxides and high-spin molecules.

Funder

Ministry of Science and Higher Education

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/28/22/7661/pdf

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