Was Pauling Mistaken about Metals?

Author:

Savin AndreasORCID

Abstract

Pauling described metallic bonds using resonance. The maximum probability domains in the Kronig–Penney model can show a picture of it. When the walls are opaque (and the band gap is large) the maximum probability domain for an electron pair essentially corresponds to the region between the walls: the electron pairs are localized within two consecutive walls. However, when the walls become transparent (and the band gaps closes), the maximum probability domain can be moved through the system without a significant loss in probability.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Reference9 articles.

1. The Nature of the Chemical Bond and the Structure of Molecules and Crystals;Pauling,1960

2. Quantum mechanics of electrons in crystal lattices;De Kronig;Proc. Roy Soc. Lond. A,1931

3. On the localizability of particles in the nuclei and in the electron cortege of atoms and molecules;Daudel;C. R. Acad. Sci. France,1953

4. Reviews of Modern Quantum Chemistry: A Celebration of the Contributions of Robert G. Parr;Savin,2002

5. How electrons guard the space: shape optimization with probability distribution criteria

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