Iodine(V)-Based Oxidants in Oxidation Reactions

Author:

Shetgaonkar Samata E.1,Jothish Subhiksha2,Dohi Toshifumi3ORCID,Singh Fateh V.2ORCID

Affiliation:

1. School of Chemical Sciences, Goa University, Taleigao Plateau 403206, Goa, India

2. Chemistry Division, School of Advanced Sciences (SAS), Vellore Institute of Technology, Chennai 600127, Tamil Nadu, India

3. College of Pharmaceutical Sciences, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatsu 525-0058, Shiga, Japan

Abstract

The chemistry of hypervalent iodine reagents has now become quite valuable due to the reactivity of these compounds under mild reaction conditions and their resemblance in chemical properties to transition metals. The environmentally friendly nature of these reagents makes them suitable for Green Chemistry. Reagents with a dual nature, such as iodine(III) reagents, are capable electrophiles, while iodine(V) reagents are known for their strong oxidant behavior. Various iodine(V) reagents including IBX and DMP have been used as oxidants in organic synthesis either in stoichiometric or in catalytic amounts. In this review article, we describe various oxidation reactions induced by iodine(V) reagents reported in the past decade.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Reference113 articles.

1. Wirth, T. (2003). Hypervalent Iodine Chemistry Modern Developments in Organic Synthesis, Springer.

2. Zhdankin, V.V. (2013). Hypervalent Iodine Chemistry: Preparation, Structure, and Synthetic Applications of Polyvalent Iodine Compounds, Wiley.

3. Knochel, P., and Molander, G. (2014). Thomas Wirth, in Comprehensive Organic Synthesis II, Elsevier.

4. Muñiz, K. (2017). Science of Synthesis: Catalytic Oxidation in Organic Synthesis, Thieme.

5. Olofsson, B., Ilan, M., and Zvi, R. (2018). The Chemistry of Hypervalent Halogen Compounds, John Wiley & Sons, Ltd.

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