Abstract
The paper presents the results obtained in studying glycerol hydrogenolysis into 1-propanol and 2-propanol over bifunctional Ni/WO3-TiO2 and Ni/WO3-ZrO2 catalysts in the flow system. Due to the optimal combination of acidic and hydrogenation properties of the heterogeneous catalysts, they exhibit higher performance in glycerol conversion into C3 alcohols, although the process is carried out in rather mild conditions. At the reaction temperature of 250 °C and hydrogen pressure of 3 MPa, the total yield of 1-propanol and 2-propanol reaches 95%, and the glycerol conversion is close to 100%.
Funder
Russian Science Foundation
Ministry of Science and Higher Education of the Russian Federation
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Cited by
8 articles.
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