Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes-Reference-Cited by-同舟云学术

Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes

Published:2023-05-13 Issue:10 Volume:28 Page:4082
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Yang Jinbo¹,Cao Xiangxue¹,Wei Lanfeng¹,Zhang Jianshu¹,Zhang Jinli²^ORCID,Liu Ping¹,Xu Liang¹^ORCID,Li Pengfei³

Affiliation:

1. State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, School of Chemistry and Chemical Engineering, Shihezi University, Beisi Road, Xinjiang Uygur Autonomous Region, Shihezi 832003, China

2. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

3. State Key Laboratory for Mechanical Behavior of Materials, Frontier Institute of Science and Technology, Xi’an Jiaotong University, Xi’an 710054, China

Abstract

Herein, a four-coordinated organoboron compound, aminoquinoline diarylboron (AQDAB), is utilized as the photocatalyst in the oxidation of silane to silanol. This strategy effectively oxidizes Si–H bonds, affording Si–O bonds. Generally, the corresponding silanols can be obtained in moderate to good yields at room temperature under oxygen atmospheres, representing a green protocol to complement the existing preparation methods for silanols.

Funder

National Natural Science Foundation of China

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/28/10/4082/pdf

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