A Strategy for Studying Environmental Engineering: Simple Hydrothermal Synthesis of Flower-Shaped Stannous Sulfide Nanomaterials for Efficient Cataluminescence Sensing of Diethyl Ether

Author:

Sun Bai12ORCID,Fan Jingjie1,Tang Zhuo1,Shi Guoji1,Yi Mingjian1ORCID,Wang Yun1,Wang Xiangxiang1,Guo Yuxian3,Zhu Shuguang1

Affiliation:

1. Anhui Institute of Urban and Rural Green Development and Urban Renewal, College of Environment and Energy Engineering, Anhui Jianzhu University, Hefei 230601, China

2. Environmental Materials and Pollution Control Laboratory, Hefei Institute of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

3. College of Mathematics and Physics, Anhui Jianzhu University, Hefei 230601, China

Abstract

In this work, flower-like stannous sulfide (SnS) nanomaterials are synthesized using a hydrothermal method and used as sensitive materials for cataluminescence (CTL)-based detection of diethyl ether. Gas sensors based on SnS nanomaterials are prepared, and the SnS nanomaterials exhibit excellent gas-sensitive behavior towards ether. High sensitivity to ether is achieved at a relatively low operating temperature (153 °C) compared to other common sensors. The response time is 3 s and the recovery time is 8 s. The CTL intensity shows a good linear relationship (R2 = 0.9931) with a detection limit of 0.15 ppm and the concentration of ether in the range of 1.5–60 ppm. The proposed CTL sensor shows good selectivity towards ether. In addition, a highly stable signal is obtained with a relative standard deviation of 1.5%. This study indicates that the SnS-based sensor has excellent gas-sensitive performance and shows potential for applications in the detection of ether.

Funder

2022 Provincial Quality Engineering Project for Higher Education Institutions of the Anhui Province

2020 Scientific Research Start-Up Foundation for the Introduction of Talent of the Anhui Jianzhu University

Natural Science Research Project of the Higher Education Institutions of the Anhui Province

National Natural Science Foundation of China

Natural Science Foundation of the Anhui Province

the first batch of natural science projects supported by surplus funds in 2021 from the Anhui Jianzhu University

2016 Scientific Research Start-Up Foundation for the Introduction of Talent of the Anhui Jianzhu University

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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