The Au25(pMBA)17Diglyme Cluster-Reference-Cited by-同舟云学术

The Au25(pMBA)17Diglyme Cluster

Published:2021-04-28 Issue:9 Volume:26 Page:2562
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Armstrong James,Ackerson Chris J.

Abstract

A modification of Au25(pMBA)18 that incorporates one diglyme ligand as a direct synthetic product is reported. Notably the expected statistical production of clusters containing other ligand stoichiometries is not observed. This Au25(pMBA)17diglyme product is characterized by electrospray ionization mass spectrometry (ESI-MS) and optical spectroscopy. Thiolate for thiolate ligand exchange proceeds on this cluster, whereas thiolate for diglyme ligand exchange does not.

Funder

National Science Foundation

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/26/9/2562/pdf

Reference23 articles.

1. Structural and Theoretical Basis for Ligand Exchange on Thiolate Monolayer Protected Gold Nanoclusters

2. Structural Basis for Ligand Exchange on Au25(SR)18

3. Biocompatible gold nanoclusters: synthetic strategies and biomedical prospects

4. Engineering ultrasmall water-soluble gold and silver nanoclusters for biomedical applications

5. Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters

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1. Effects of Diglyme on Au Nanocluster Formation: Mechanism, ¹H NMR, and Bonding;The Journal of Physical Chemistry A;2022-10-12

2. An ultrastable thiolate/diglyme ligated cluster: Au₂₀(PET)₁₅(DG)₂;Nanoscale;2022