Enhancing Cu2+ Ion Removal: An Innovative Approach Utilizing Modified Frankincense Gum Combined with Multiwalled Carbon Tubes and Iron Oxide Nanoparticles as Adsorbent

Author:

Hussain Mushtaq1,Hussaini Syed Sulaiman1ORCID,Shariq Mohammad2ORCID,Alzahrani Hanan2ORCID,Alholaisi Arafa A.3,Alharbi Samar H.3,Alsharif Sirajah A.3,Al-Gethami Wafa4,Ali Syed Kashif5,Alaghaz Abdel-Nasser M. A.5,Siddiqui Mohd Asim1,Seku Kondaiah1ORCID

Affiliation:

1. Engineering Department, College of Engineering and Technology, University of Technology and Applied Sciences, Shinas 324, Oman

2. Department of Physics, College of Science, Jazan University, Jazan 45142, Saudi Arabia

3. Department of Physics, Al-Qunfudah University College, Umm Al-Qura University, Makkah 24382, Saudi Arabia

4. Chemistry Department, Faculty of Science, Taif University, Al-Hawiah, Taif City P.O. Box 11099, Saudi Arabia

5. Department of Chemistry, College of Science, Jazan University, Jazan 45142, Saudi Arabia

Abstract

Aquatic pollution, which includes organic debris and heavy metals, is a severe issue for living things. Copper pollution is hazardous to people, and there is a need to develop effective methods for eliminating it from the environment. To address this issue, a novel adsorbent composed of frankincense-modified multi-walled carbon nanotubes (Fr-MMWCNTs) and Fe3O4 [Fr-MWCNT-Fe3O4] was created and subjected to characterization. Batch adsorption tests showed that Fr-MWCNT-Fe3O4 had a maximum adsorption capacity of 250 mg/g at 308 K and could efficiently remove Cu2+ ions over a pH range of 6 to 8. The adsorption process followed the pseudo-second-order and Langmuir models, and its thermodynamics were identified as endothermic. Functional groups on the surface of modified MWCNTs improved their adsorption capacity, and a rise in temperature increased the adsorption efficiency. These results highlight the Fr-MWCNT-Fe3O4 composites’ potential as an efficient adsorbent for removing Cu2+ ions from untreated natural water sources.

Funder

Ministry of Higher Education, Research, and Innovation (MoHERI), Sultanate of Oman

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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