Abstract
The paper presents the preparation of new ionic liquids based on hexamethylenetetramine with bis(trifluoromethanesulfonyl)imide and dicyanamide anion, which were characterized in detail in terms of their purity (Ion Chromatography) and thermal properties (Differential Scanning Calorimetry), as well as stability. The obtained substances were used to develop curing systems with ethylene glycol, which were successfully tested for their application with bisphenol A diglycidyl ether molecule. In addition, the curing process and its relationship to the structure of the ionic liquid are characterized in detail. The research showed that hexamethylenetetramine-based new ionic liquids can be successfully designed using well-known and simple synthetic methods—the Delepine reaction. Moreover, attention was paid to their stability, related limitations, and the application of hexamethylenetetramine-based ionic liquids in epoxy-curing systems.
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Reference50 articles.
1. Synthesis and Application of Epoxy Resins: A Review;Jin;J. Ind. Eng. Chem.,2015
2. Epoxy Resin Composite Reinforced with Carbon Fiber and Inorganic Filler: Overview on Preparation and Properties;Rafique;Polym.-Plast. Technol. Eng.,2016
3. Rezaei Motlagh, S., Harun, R., Awang Biak, D.R., Hussain, S.A., Wan Ab Karim Ghani, W.A., Khezri, R., Wilfred, C.D., and Elgharbawy, A.A.M. (2019). Screening of Suitable Ionic Liquids as Green Solvents for Extraction of Eicosapentaenoic Acid (EPA) from Microalgae Biomass Using COSMO-RS Model. Molecules, 24.
4. How Does Ionic Liquid Play a Role in Sustainability of Biomass Processing?;Khoo;J. Clean. Prod.,2021
5. Ionic Liquids: A Milestone on the Pathway to Greener Recycling of Cellulose from Biomass;Rieland;Resour. Conserv. Recycl.,2020
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