Abstract
Deamination of 1-aminoalkylphosphonic acids in the reaction with HNO2 (generated “in situ” from NaNO2) yields a mixture of substitution products (1-hydroxyalkylphosphonic acids), elimination products (vinylphosphonic acid derivatives), rearrangement and substitution products (2-hydroxylkylphosphonic acids) as well as H3PO4. The variety of formed reaction products suggests that 1-phosphonoalkylium ions may be intermediates in such deamination reactions.
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Reference88 articles.
1. C–P natural products as next-generation herbicides: Chemistry and biology of glufosinate;Zhou;J. Agric. Food Chem.,2020
2. Review on modern advances of chemical methods for the introduction of a phosphonic acid group;Demmer;Chem. Rev.,2011
3. Phosphine organocatalysis;Guo;Chem. Rev.,2018
4. Phosphorus-containing fluoropolymers: State of the art and applications;Wehbi;ACS Appl. Mater. Interfaces,2020
5. Wendels, S., Chavez, T., Bonnet, M., Salmeia, K.A., and Gaan, S. (2017). Recent developments in organophosphorus flame retardants containing P-C bond and their applications. Materials, 10.
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