Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups-Reference-Cited by-同舟云学术

Synthesis and Characterization of Bulky Substituted Hemihexaphyrazines Bearing 2,6-Diisopropylphenoxy Groups

Published:2023-07-29 Issue:15 Volume:28 Page:5740
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Ivanov Evgenii N.¹²,Almeida-Marrero Verónica³,Koifman Oskar I.¹²,Aleksandriiskii Viktor V.¹²^ORCID,Torres Tomas³⁴⁵^ORCID,Islyaikin Mikhail K.¹²^ORCID

Affiliation:

1. IRLoN, Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 7, Sheremetievskiy Ave., 153000 Ivanovo, Russia

2. G. A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, 1 Akademicheskaya Str., 153045 Ivanovo, Russia

3. Department of Organic Chemistry, Autonoma University of Madrid, Cantoblanco, 28049 Madrid, Spain

4. Institute for Advanced Research in Chemical Sciences (IAdChem), Autonoma University of Madrid, 28049 Madrid, Spain

5. Instituto Madrileño de Estudios Avanzados (IMDEA)—Nanociencia, c/Faraday 9, Cantoblanco, 28049 Madrid, Spain

Abstract

New substituted [30]trithiadodecaazahexaphyrines (hemihexaphyrazines) were synthesized by a crossover condensation of 2,5-diamino-1,3,4-thiadiazole with 4-chloro-5-(2,6-diisopropylphenoxy)- or 4,5-bis-(2,6-diisopropylphenoxy)phthalonitriles. The compounds were characterized by 1H-, 13C-NMR, including COSY, HMBC, and HSQC spectroscopy, MALDI TOF spectrometry, elemental analysis, IR and UV-Vis absorbance and fluorescence techniques.

Funder

Ministry of Science and Higher Education of the Russian Federation

Center for Shared Use of Scientific Equipment of the ISUCT

MICINN

Comunidad de Madrid

Spanish State

European Union

“Severo Ochoa” Programme for Centres of Excellence in R & D

Institute for Advanced Research in Chemical Sciences (IAdChem), Autonoma University of Madrid

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/28/15/5740/pdf

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