Strategies for Improving Sustainability in the Development of High-Performance Styrenic Block Copolymers by Developing Blends with Cellulose Derivatives

Author:

Pajares Erika12,Maestu Josu Fernández1ORCID,Fernandez-de-Mendiola Irati13,Silvan Unai14,Costa Pedro5ORCID,Agirrezabal-Telleria Iker2,Tubio Carmen R.1ORCID,Corona-Galván Sergio6,Lanceros-Mendez Senentxu145ORCID

Affiliation:

1. BCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, 48940 Leioa, Spain

2. Sustainable Process Engineering Group, Department of Chemical and Environmental Engineering, University of the Basque Country (UPV/EHU), 48013 Bilbao, Spain

3. Department of Cell Biology and Histology, Faculty of Medicine and Nursing, University of the Basque Country (UPV/EHU), 48940 Leioa, Spain

4. IKERBASQUE, Basque Foundation for Science, 48009 Bilbao, Spain

5. Physics Center of Minho and Porto Universities (CF-UM-UP) and LaPMET—Laboratory of Physics for Materials and Emergent Technologies, University of Minho, 4710-057 Braga, Portugal

6. Dynasol, Titán 15, 9th Floor, 28045 Madrid, Spain

Abstract

Next-generation high-performance polymers require consideration as sustainable solutions. Here, to satisfy these criteria, we propose to combine high-performance styrenic block copolymers, a class of thermoplastic elastomer, with cellulose derivatives as a reinforcing agent with the aim of maintaining and/or improving structural and surface properties. A great advantage of the proposed blends is, besides their biocompatibility, a decrease in environmental impact due to blending with a natural polymer. Particularly, we focus on identifying the effect of different blending compounds and blend ratios on the morphological, structural, thermal, mechanical, electrical and cytotoxic characteristics of materials. This research provides, together with novel material formulations, practical guidelines for the design and fabrication of next-generation sustainable high-performance polymers.

Funder

Basque Government Industry Department

Publisher

MDPI AG

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