Development of an Innovative Lightweight Composite Material with Thermal Insulation Properties Based on Cardoon and Polyurethane

Author:

Fernandes Raquel A.123,Ferreira Nuno1,Lopes Sandro1,Santos Jorge123ORCID,Bento Pereira Nelson45,Ferreira Nuno Oliveira56ORCID,Nunes Lina7ORCID,Martins Jorge M.238,Carvalho Luisa H.238ORCID

Affiliation:

1. ARCP Colab—Rede de Competências em Polímeros, Rua Júlio de Matos, 828/882, 4200-355 Porto, Portugal

2. LEPABE—Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s/n, 4200-465 Porto, Portugal

3. AliCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal

4. CICon—Center for Innovation in Construction, Zona Industrial de Sabroso de Aguiar-Lote 2B, 5450-371 Vila Pouca de Aguiar, Portugal

5. CEPAT—Center for Heritage Studies, Avenida do Conde 5643, 4465-097 São Mamede de Infesta, Portugal

6. Secundino Queirós Construction, Avenida Lopes de Oliveira 29, 5450-140 Pedras Salgadas, Portugal

7. LNEC—Laboratório Nacional de Engenharia Civil, Structures Department, Av. do Brasil, 101, 1700-066 Lisbon, Portugal

8. DEMad—Department of Wood Engineering, Instituto Politécnico de Viseu, Campus Politécnico de Repeses, 3504-510 Viseu, Portugal

Abstract

The search for innovative and sustainable solutions to improve the energy efficiency of the construction industry has been a hot topic for researchers due to the tremendous impact of insulator materials in the thermal comfort of buildings. In the present work, an innovative lightweight composite material with thermal insulation properties was developed, for the first time, by using cardoon particles and polyurethane. The formulation of the composite material was optimized in terms of cardoon fraction and the polyol/isocyanate ratio, to achieve the best compromise between internal bond (IB) strength and thickness swelling (TS). The best performing composite was PU75-CP45, with 45 wt% of cardoon particles and 75% of isocyanate, achieving an IB of 0.41 MPa and a TS of 5.3%. Regarding insulation properties, the PU75-CP45 composite material exhibits a promising performance when compared to conventional construction industry materials by tuning its thickness. Additionally, the composite material presented very low emissions of volatile organic compounds and formaldehyde (bellow to legislation levels) and high resistance to biological degradation.

Funder

ALiCE

LEPABE

FEDER

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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