Synthesis of Monodisperse Mesoporous Carbon Spheres/EPDM Rubber Composites and Their Enhancement Mechanical Properties

Author:

Zheng Tong1,Jia Wenjing1,Meng Hongjie2,Li Jiajie1,Liu Xundao1

Affiliation:

1. School of Material Science and Engineering, University of Jinan, Jinan 250022, China

2. Shanghai Key Lab of Electrical Insulation and Thermal Aging, School of Chemistry and Chemical Engineering, Center of Hydrogen Science, Shanghai Jiao Tong University, Shanghai 200240, China

Abstract

Monodisperse mesoporous carbon spheres (MCS) were synthesized and their potential applications in ethylene propylene diene monomer (EPDM) foam were evaluated. The obtained MCS exhibited a high specific surface area ranging from 621-to 735 m2/g along with large pore sizes. It was observed that the incorporation of MCS into EPDM foam rubber significantly enhances its mechanical properties. The prepared MCS-40 rubber composites exhibit the highest tear strength of 210 N/m and tensile strength of 132.72 kPa, surpassing those of other samples. The enhancement mechanism was further investigated by employing computer simulation technology. The pores within the MCS allowed for the infiltration of EPDM molecular chains, thereby strengthening the interaction forces between the filler and matrix. Moreover, a higher specific surface area resulted in greater adsorption of molecular chains onto the surface of these carbon spheres. This research offers novel insights for understanding the enhancement mechanism of monodisperse mesoporous particles/polymer composites (MCS/EPDM) and highlights their potential application in high-performance rubber composites.

Funder

Science and Technology Program of the University of Jinan

Publisher

MDPI AG

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