Affiliation:
1. Key Laboratory for New Type of Functional Materials in Hebei Province, Tianjin Key Laboratory Material Laminating Fabrication and Interface, Tianjin Engineering and Technology Centre for Environmental-Friendly Coating on Pipeline, School of Materials Science and Engineering, Hebei University of Technology, Tianjin 300132, China
Abstract
In this study, the impact of various temperatures (25 °C, 45 °C, and 55 °C) on q235 steel specimens was studied to analyze the influence on the morphology and corrosion resistance of modified boron nitride nanosheets incorporated into the phosphate coating. The morphology and surface modification of the coating were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). SEM results showed that the S-45 steel sample produced a higher number of nucleation sites and reduced grain size with a denser, more robust, and more corrosion-resistant phosphate coating compared to the S-25 and S-55 samples, respectively. The potentiodynamic polarization results demonstrate that the S-45 steel sample exhibited the best corrosion resistance performance with an electric current density of 5.48 × 10−8 A/cm2, an order of magnitude lower than the S-25 and S-55 samples, respectively. The coating weight results showed that the S-45 steel specimen achieved the densest and most uniform coating (32.14 g/m2).
Funder
National Natural Science Foundation of China
Hebei Province Science and Technology Support Program
Subject
General Materials Science,Metals and Alloys
Reference36 articles.
1. Tarka, K., Jaako, A., Persson, D., Mattsson, H., and Johansson, L.-G. (2015). Sustainable Automotive Technologies 2014, Springer International Publishing.
2. Corrosion mechanisms of phosphated zinc layers on steel as substrates for automotive coatings;Amirudin;Prog. Org. Coat.,1996
3. Current status, opportunities and challenges in chemical conversion coatings for zinc;Gao;Colloids Surf. A Physicochem. Eng. Asp.,2018
4. Corrosion behaviour in alkaline medium of zinc phosphate coated steel obtained by cathodic electrochemical treatment;Simescu;Corros. Sci.,2009
5. The Influence of Deposition Temperature on the Morphology and Corrosion Resistance of Zinc Phosphate Coating on Mild Steel;Abdalla;Adv. Mater. Res.,2012