A Comparative Thermoacoustic Insulation Study of Silica Aerogels Reinforced with Reclaimed Textile Fibres: Cotton, Polyester and Wool

Author:

Linhares Teresa12,Carneiro Vitor H.345,Pessoa de Amorim Maria T.2ORCID,Durães Luisa1ORCID

Affiliation:

1. University of Coimbra, CIEPQPF, Department of Chemical Engineering, 3030-790 Coimbra, Portugal

2. 2C2T-Centre for Textile Science and Technology, University of Minho, Campus of Azurém, 4800-058 Guimarães, Portugal

3. CMEMS, University of Minho, Campus of Azurém, 4800-058 Guimarães, Portugal

4. Department of Engineering, Universidade de Trás-os-Montes e Alto Douro, Quinta de Prados, 5001-801 Vila Real, Portugal

5. Metrics, University of Minho, Campus of Azurém, 4800-058 Guimarães, Portugal

Abstract

Silica aerogels are highly porous materials with exceptional thermal insulation performance. They become even more attractive if combined thermal and acoustic insulation is achieved. Silica aerogel composites reinforced with fibres are an ingenious way to surpass the fragility stemmed from the aerogel’s intrinsic porosity, and textile fibres are good sound absorption materials. Reclaimed fibres are a relatively low-cost feedstock and were obtained in this work exclusively through mechanical processes from textile wastes, thus promoting the concept of circular economy, namely for cotton, polyester and wool fibres. These reclaimed fibres were used as reinforcement matrices for silica aerogel composites obtained from sol–gel transformation of tetraethyl orthosilicate and isobutyltriethoxysilane/or vinyltrimethoxysilane precursors and dried at ambient pressure after silylation. Silica aerogel composites reinforced with reclaimed cotton fibres had the best sound absorption coefficient (a peak value of 0.89), while the polyester-reinforced composite exhibited the lowest thermal conductivity (k = ~24 mW m−1 K−1, Hot Disk). The better combined results on thermal and acoustic insulation were achieved by the wool-reinforced composites. The thermal conductivity values were less than 27 mW m−1 K−1, and the sound absorption coefficient achieved a peak value of 0.85. Therefore, the aerogel composites developed here can be selected for thermal or/and acoustic barriers by choosing a suitable type of fibre. Their design and preparation protocol followed environmental-friendly and cost-effective approaches.

Funder

Fundação para a Ciência e Tecnologia, I.P.

MCTES

European Commission through the European Social Fund

European Regional Development Fund

Publisher

MDPI AG

Subject

Polymers and Plastics,Organic Chemistry,Biomaterials,Bioengineering

Reference91 articles.

1. Deshpande, R., Smith, D.M., and Brinker, C.J. (1996). Preparation of High Porosity Xerogels by Chemical Surface Modification. (No. 5,565,142A), U.S. Patent.

2. Aegerter, M.A., Leventis, N., and Koebel, M.M. (2011). Aerogels Handbook, Springer Science+Business Media.

3. Sachithanadam, M., and Joshi, S.C. (2016). Silica Aerogel Composites Novel Fabrication Methods, Springer.

4. Silica Aerogel Composites with Embedded Fibres: A Review on Their Preparation, Properties and Applications;Linhares;J. Mater. Chem. A,2019

5. Textile Exchange (2022). Preferred Fiber & Materials: Market Report 2022, Textile Exchange.

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