Water Vapor Sorption Kinetics of Beech Wood Modified with Phenol Formaldehyde Resin Oligomers

Author:

Lang Qian1,Biziks Vladimirs2ORCID,Militz Holger2ORCID

Affiliation:

1. Faculty of Engineering, Northeast Agricultural University, Harbin 150030, China

2. Wood Biology and Wood Product, Burckhardt-Institute, Georg-August University of Göttingen, Büsgenweg 4, 37077 Goettingen, Germany

Abstract

Beech is an important tree species in Europe. This study aimed to elucidate the influence of four molecular weights of phenol formaldehyde (PF) resin (266, 286, 387, and 410 g/mol) on the sorption behavior of unmodified and modified beech wood samples using a dynamic vapor sorption (DVS) apparatus. The variations in the environmental relative humidity and moisture content (MC) of the samples were recorded, and the DVS isotherms were plotted from the equipment. During the sorption process, the MC of the modified samples decreased in comparison to that of the unmodified samples, and both apparently decreased with the increasing molecular weight of the PF resin. The DVS isotherm hysteresis plot illustrated a reduction in sorption hysteresis for the modified wood with varying PF resins compared to the unmodified samples. Based on the DVS isotherm adsorption and desorption plots, the decrease in the equilibrium of the MC can be attributed to there being fewer sorption sites in the modified samples, which exhibited the lowest hygroscopicity. Overall, the moisture sorption mechanism for both types of samples was clarified, highlighting a clear correlation between the molecular weight of the applied PF resin and its influence on moisture sorption behavior.

Funder

Heilongjiang Province Natural Science Foundation

China Postdoctoral Science Foundation

Heilongjiang Province Postdoctoral Science Foundation

Publisher

MDPI AG

Subject

Forestry

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