Changing Air Quality and the Ozone Weekend Effect during the COVID-19 Pandemic in Toronto, Ontario, Canada

Abstract

Air pollutants, NO, NO2, and O3, were examined from April to June 2020 and compared to a 10-year (2010–2019) climatology of these pollutants for two monitoring sites in Toronto, Ontario, Canada, coinciding with local lockdown measures during the first wave of the COVID-19 pandemic. NO and NO2 values were lower than any of the preceding 10 years at the two Toronto sites for both weekdays and weekends. Ozone concentrations did not have a corresponding decrease and in fact increased for weekdays, similar to other parts of the world. The well-documented ozone weekend effect was considerably muted during the morning rush hour throughout this pandemic period. A Fisher exact test on hourly averaged data revealed statistically significant record hourly minimums for NO and NO2, but this was not found for ozone, consistent with the aggregate ranking results. These findings are likely the result of considerably reduced vehicular traffic during this time and ozone chemistry in a NOx-saturated (VOC limited) environment. This has important implications for ozone abatement strategies.