Effect of Rotary Swaging on Mechanical and Operational Properties of Zn–1%Mg and Zn–1%Mg–0.1%Ca Alloys

Author:

Martynenko Natalia1ORCID,Anisimova Natalia123ORCID,Rybalchenko Georgy4,Rybalchenko Olga1ORCID,Serebryany Vladimir1,Zheleznyi Mark156,Shinkareva Maria13,Gorbenko Artem1,Temralieva Diana1,Lukyanova Elena1,Sannikov Andrey17ORCID,Koltygin Andrey7ORCID,Kiselevskiy Mikhail23,Yusupov Vladimir1,Dobatkin Sergey1

Affiliation:

1. A.A. Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences, Leninskiy Prospect, 49, 119334 Moscow, Russia

2. N.N. Blokhin National Medical Research Center of Oncology (N.N. Blokhin NMRCO) of the Ministry of Health of the Russian Federation, 115478 Moscow, Russia

3. Center for Biomedical Engineering, National University of Science and Technology “MISIS”, 119049 Moscow, Russia

4. P.N. Lebedev Physical Institute of the Russian Academy of Sciences, 119991 Moscow, Russia

5. Department of Physical Materials Science, National University of Science and Technology “MISIS”, 119049 Moscow, Russia

6. Institute of Innovative Engineering Technologies, Peoples’ Friendship University of Russia (RUDN University), 117198 Moscow, Russia

7. Department of Casting Technologies and Artistic Processing of Materials, National University of Science and Technology “MISIS”, 119049 Moscow, Russia

Abstract

A study of microstructure, phase composition, mechanical properties, corrosion processes, and biocompatibility in vitro of the Zn–1%Mg and Zn–1%Mg–0.1%Ca alloys in an annealed state and after rotary swaging (RS) is presented. Partially recrystallized microstructure is formed in the studied alloys after RS at 200 °C. RS reduces the mass fraction of intermetallic phases in comparison with annealed states of the alloys. RS at 200 °C increases the strength of the Zn–1%Mg and Zn–1%Mg–0.1%Ca alloys up to 248 ± 9 and 249 ± 9 with the growth of ductility up to 10.3 ± 3% and 14.2 ± 0.9%, respectively. The structure after RS at 200 °C does not lead to a change in the corrosion resistance of the studied alloys. However, an increase in the incubation period of the alloys in a growth medium slows down the degradation process due to the formation of a film consisting of degradation products. Rotary swaging does not impair the biocompatibility of the Zn–1%Mg and Zn–1%Mg alloys, maintaining the viability and integrity of blood cells, preventing hemolysis, and ensuring the adhesion and proliferation of osteogenic cells on the surface of samples.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

General Materials Science,Metals and Alloys

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