Application of Elemental Geochemistry in High-Frequency Sequence—Stratigraphic Analysis of Lacustrine Shale

Abstract

The successful development of shale gas and oil in North America has created considerable interest in shale. The analysis of genetic types, the sedimentary environment, and the mudstone development mechanism within sequences is critical for evaluating shale gas and oil exploration prospects, exploration favorable zones, and resource potential. This study focused on the shale of Shahejie Formation in Dongying Depression of Bohai Bay Basin. Shale lithofacies division, geochemical analysis, and well-log analysis were performed for a sedimentary environment and its related elemental response characteristics’ identification. Based on the results, we concluded that the sedimentary environment of the lake basin evolved from the saltwater lake to the ambiguous lake and then the open lake to the delta. In response, we observed gradually decreasing Sr/Ba and Ca/Mg ratios and increasing Rb/Ca and Fe/Mn ratios during the whole process during the reduction of the salinity and the decrease in PH value and sediments’ transport distance. The relationship between ratio elements and high-frequency sequences was initially established within the shale strata. Our results show that ratios of Sr/Ba and Ca/Mg ratios near the sequence boundary are relatively low, and ratios of Fe/Mn and Rb/Ca are relatively high, while ratios of Sr/Ba and Ca/Mg near the flooding surface are relatively high, and ratios of Fe/Mn and Rb/Ca are relatively low. Those features can be used as a marker for high-frequency sequence division of shale strata. Our results provided a new theoretical basis and technical method for shale gas and oil exploration and development.