About the Origin of Carbonado

Author:

Afanasiev Valentin1ORCID,Kovalevsky Vladimir2ORCID,Yelisseyev Alexander1ORCID,Mashkovtsev Rudolf1ORCID,Gromilov Sergey34,Ugapeva Sargylana5ORCID,Barabash Ekaterina1,Ivanova Oksana1,Pavlushin Anton5ORCID

Affiliation:

1. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090, Russia

2. Geological Institute of Kola Science Centre, Russian Academy of Sciences, Apatity 184209, Russia

3. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russia

4. Department of Physics, Novosibirsk State University, Novosibirsk 630090, Russia

5. Diamond and Precious Metal Geology Institute, Siberian Branch, Russian Academy of Science, Yakutsk 677000, Russia

Abstract

Carbonado is a specific variety of diamonds, typical representatives of which are distributed in the diamond placers of Central Africa, Brazil, and Venezuela. Carbonado consists of the microcrystalline aggregates of diamonds, with inclusions of mineral matter. These aggregates appear as fragments that are rounded to varying degrees. Carbonado has been known for a long time, but its primary sources have not been found and its genesis remains unclear. We have substantiated the hypothesis that the most probable precursor of carbonado is shungite. Shungite is a specific form of non-crystalline, non-graphitic, fullerene-like carbon. Shungite rocks, currently known in Karelia (Russia), are natural microdispersed composite materials containing shungite—carbonaceous matter and mineral components of different compositions. The content of carbonaceous matter in shungite rocks is from less than 10% to 98%. The carbon isotopic composition of shungite is light ẟ13C from −25‰ to −40‰. The age of shungite rock is more than 2 billion years old, but earlier shungite was probably much more widespread. Known shungite rocks are more than 2 billion years old, but earlier shungite was probably much more widespread. Shungite rocks could recrystallize into diamond rock upon subduction to high pressure and temperature. The diamond rocks could then be exhumed to the Earth’s surface, where they could undergo disruption and reworking with formation of those very fragments that are known as “carbonado”.

Funder

IGM SB RAS

DPMGI SB RAS

NIIC SB RAS

IG KarRC RAS

Publisher

MDPI AG

Reference66 articles.

1. Leonardos, O.H. (1937). Diamante e Carbonado do Estado da Bahia.

2. The first finds of carbonado and a new find of ballas in the Soviet Union;Kaminsky;Dokl. Earth Sci. SSSR,1978

3. Carbonado and defective crystals among small diamonds from kimberlites;Argunov;Mineral. J.,1985

4. Carbonado: Diamond aggregates from early impacts of crustal rocks?;Smith;Geology,1985

5. Some questions of terminology of polycrystalline diamond aggregates;Kaminsky;Mineral. Collect.,1987

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