Effect of Alkaline Salts on Pyrolyzed Solid Wastes in Used Edible Oils: An Attenuated Total Reflectance Analysis of Surface Compounds as a Function of the Temperature

Abstract

Biochars obtained via the pyrolysis of biomass are very attractive materials from the point of view of their applications and play key roles in the current energy context. The characterization of these carbonaceous materials is crucial to determine their field of application. In this work, the pyrolysis of a non-conventional biomass (solid wastes in used edible oils) was investigated. The obtained biochars were characterized using conventional techniques (TG, XRD, and SEM-EDX), and a deep analysis via ATR-FTIR was performed. This spectroscopic technique, which is a rapid and powerful tool that is well adapted to study carbon-based materials, was employed to determine the effect of temperature on the nature of functional groups on the surface. Moreover, the water washing of the raw sample (containing important quantities of inorganic salts) before pyrolysis evidenced that the inorganic salts act as catalysts in the biomass degradation and influence the degree of condensation (DOC) of PAH. Moreover, it was observed that these salts contribute to the retention of oxygenated compounds on the surface of the solid.