Reutilization of Reclaimed Asphalt Binder via Co-Pyrolysis with Rice Husk: Thermal Degradation Behaviors and Kinetic Analysis

Abstract

Realizing the utilization of reclaimed asphalt binder (RAB) and rice husk (RH) to reduce environmental pollution and expand the reutilization technique of reclaimed asphalt pavement (RAP), co-pyrolysis of RAB with RH has great potential. In this study, the co-pyrolysis behaviors, gaseous products, and kinetics were evaluated using thermogravimetric analysis and Fourier transform infrared spectroscopy (TG-FTIR). The results showed that incorporating RH into RAB improved its pyrolysis characteristics. The interactions between RAB and RH showed initial inhibition followed by subsequent promotion. The primary gaseous products formed during co-pyrolysis were aliphatic hydrocarbons, water, and carbon dioxide, along with smaller amounts of aldehydes and alcohols originating from RH pyrolysis. All average activation energy values for the blends, determined through iso-conversional methods, decreased with RH addition. The combined kinetic analysis revealed two distinct mechanisms: (1) at the lower conversion range, the pyrolysis of the blend followed a random nucleation and three-dimensional growth mechanism, while (2) at the higher conversion range, the control mechanism transitioned into three-dimensional diffusion.