Efficient Vanadate Removal by Mg-Fe-Ti Layered Double Hydroxide

Author:

Guo Yanwei,Lu Hongtao,Han Bangjun,Zou Tiemei,Zhu ZhiliangORCID

Abstract

A series of novel layered double hydroxides (Mg-Fe-Ti-LDHs) containing Mg2+, Fe3+ and Ti4+ were prepared. The adsorption performance of Mg-Fe-Ti-LDHs on vanadate in aqueous solution was investigated and the effects of various factors on the adsorption process were examined, including initial vanadate concentration, adsorbent dosage, contact time, solution pH and coexisting ions. A preliminary discussion of the adsorption mechanism of vanadate was also presented. Results show that the adsorption efficiency of vanadate increased with the introduction of Ti4+ into the laminate of LDHs materials. The adsorption capacity of the materials also differed for different anion intercalated layers, and the Mg-Fe-Ti-LDHs with Cl− intercalation showed higher vanadate removal compared to the CO32− intercalated layer. Furthermore, Mg-Fe-Ti-CLDH showed higher vanadate removal compared to pre-calcination. The adsorption experimental data of vanadate on Mg-Fe-Ti-LDHs were consistent with the Langmuir adsorption isotherm model and the adsorption kinetics followed a pseudo-second order kinetic model. The pH of the solution significantly affected the vanadate removal efficiency. Meanwhile, coexisting ions PO43−, SO42− and NO3− exerted a significant influence on vanadate adsorption, the magnitude of the influence was related to the valence state of the coexisting anions. The possible adsorption mechanisms can be attributed to ion exchange and layered ligand exchange processes. The good adsorption capacity of Mg-Fe-Ti-LDHs on vanadate broadens the application area of functional materials of LDHs.

Funder

National Natural Science Foundation of China

Research Project of Shanghai Urban Construction Vocational College

Publisher

MDPI AG

Subject

Water Science and Technology,Aquatic Science,Geography, Planning and Development,Biochemistry

Reference43 articles.

1. Chapter 1: Introduction: Vanadium, Its Compounds and Applications;Sutradhar,2021

2. Chapter 2—Types of inorganic pollutants: Metals/metalloids, acids, and organic forms;Borah,2020

3. Determination of vanadium species in environmental samples

4. Application of HPLC to measure vanadium in environmental, biological and clinical matrices

5. Vanadium removal by metal (hydr)oxide adsorbents

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3