The Specificity of Determining the Latent Heat of Solidification of Cast Hypoeutectic AlSiCu Alloys Using the DSC Method

Author:

Đjurdjević Mile B.1ORCID,Jovanović Vladimir2ORCID,Komatina Mirko3ORCID,Stopic Srecko4

Affiliation:

1. Department of Material Science and Technology, University of Applied Science, Roseggerstrasse 15, 46000 Wels, Austria

2. Fuel & Combustion Laboratory, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11000 Belgrade, Serbia

3. Department of Thermodynamics, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11000 Belgrade, Serbia

4. IME Process Metallurgy and Metal Recycling, RWTH Aachen University, Intzestrasse 3, 52056 Aachen, Germany

Abstract

Latent heat is commonly measured using Differential Thermal Analysis (DTA) or Differential Scanning Calorimetry (DSC) or calculated using software packages (Thermo-Calc). In this study, the DSC method was used to comprehensively evaluate the accuracy of calculated latent heat for a specific range of cast AlSiCu alloys, considering their solidification under different cooling conditions. The tests involved varying concentrations of two crucial alloying elements: wSi (5, 7, and 9%) and wCu (1, 2, and 4%). All selected alloys were analyzed under three distinct cooling/heating rates: 6, 10, and 50 °C/min. The Thermo-Calc method was used in this work to calculate the latent heats of the investigated alloys. The results obtained show good agreement between the measured and calculated values. The increase in silicon content in the investigated alloys from 4.85% to 9.85% resulted in the increase in latent heat from 407.6 kJ/kg to 467.5 kJ/kg. Higher cooling rates, such as 50 °C/min, resulted in a reduced latent heat release compared to slower rates such as 10 °C/min and 6 °C/min.

Publisher

MDPI AG

Reference37 articles.

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3. Davies, J.R. (1993). Aluminium and Aluminium Alloys, ASM International.

4. Djurdjevic, M.B., Manasijevic, S., Mihailovic, M., and Stopic, S. (2023). From bauxite as critical material to required properties of cast aluminum alloys for electro automotive parts. Metals, 13.

5. Mondolfo, L.F. (1979). Aluminum Alloys, Structure and Properties, Butterworths.

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