Corrosion Resistance of the Welded Joints from the Ultrafine-Grained Near-α Titanium Alloys Ti-5Al-2V Obtained by Spark Plasma Sintering

Author:

Chuvil’deev Vladimir1ORCID,Nokhrin Aleksey1ORCID,Likhnitskii Constantin1,Kopylov Vladimir1ORCID,Andreev Pavel1ORCID,Boldin Maksim1ORCID,Tabachkova Nataliya23ORCID,Malkin Aleksander4

Affiliation:

1. Materials Science Department, Physical and Technical Research Institute, Lobachevsky State University of Nizhny Novgorod, 603022 Nizhny Novgorod, Russia

2. Center Collective Use “Materials Science and Metallurgy”, National University of Science and Technology “MISIS”, 119991 Moscow, Russia

3. Laboratory “FIANIT”, Laser Materials and Technology Research Center, A.M. Prokhorov General Physics Institute of the Russian Academy of Sciences, 119991 Moscow, Russia

4. Laboratory of Physico-Chemical Mechanics and Mechanochemistry, A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Science, 119071 Moscow, Russia

Abstract

A solid-phase diffusion welding of coarse-grained and ultrafine-grained (UFG) specimens of titanium near-α alloy Ti-5Al-2V used in nuclear power engineering was made by Spark Plasma Sintering. The failure of the welded specimens in the conditions of hot salt corrosion and electrochemical corrosion was shown to have a preferentially intercrystalline character. In the case of the presence of macrodefects, crevice corrosion of the welded joints was observed. The resistance of the alloys against the intercrystalline corrosion was found to be determined by the concentration of vanadium at the titanium grain boundaries, by the size and volume fraction of the β-phase particles, and by the presence of micro- and macropores in the welded joints. The specimens of the welded joints of the UFG alloy are harder and have a higher resistance to hot salt corrosion and electrochemical corrosion.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

General Materials Science,Metals and Alloys

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