Performance of Dye Removal from Single and Binary Component Systems by Adsorption on Composite Hydrogel Beads Derived from Fruits Wastes Entrapped in Natural Polymeric Matrix

Abstract

The treatment of contaminated water is currently a major concern worldwide. This work was directed towards the preparation of a composite hydrogel by entrapping cherry stones powder on chitosan, which is known as one of the most abundant natural polymers. The synthesized material was characterized by scanning electron microscopy, by Fourier transform infrared spectroscopy, and by the point of zero charge determination. Its ability to remove two azo dyes models (Acid Red 66 and Reactive Black 5) existing in single form and in binary mixture was evaluated. Response Surface Methodology–Central Composite Design was used to optimize three parameters affecting the process while targeting the lowest final contaminant concentrations. The best results were obtained at pH 2, an adsorbent dose of 100 g/L, and a temperature of 30 °C, when more than 90% of the pollutants from the single component systems and more than 70% of those of the binary mixtures were removed from their aqueous solutions. The adsorption process was in accordance with Elovich and pseudo-second-order kinetic models, and closely followed the Freundlich and Temkin equilibrium isotherms. The obtained results led to the conclusion that the prepared hydrogel composite possesses the ability to successfully retain the target molecules and that it can be considered as a viable adsorbent material.