ATR-FTIR Study of Alaska Yellow Cedar Extractives and Relationship with Their Natural Durability

Abstract

New approaches for assessing wood durability are needed to help categorize decay resistance as timber utilization shifts towards plantations or native forest regrowth that may be less durable than original native forest resources. This study evaluated attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy combined with principal component analysis (PCA) for distinguishing between groups of Alaska yellow cedar (Cupressus nootkatensis) wood for susceptibility to two decay fungi (Gloeophyllum trabeum and Rhodonia placenta) and the eastern subterranean termite (Reticulitermes flavipes). Alaska yellow cedar durability varied with test organisms, but the majority of samples were highly resistant to fungal and termite attack. Weight losses and extractives yield using sequential extractions (toluene:ethanol > ethanol > hot water) showed moderate to weak relationships. PCA analysis revealed limited ability to distinguish amongst levels of wood durability to all tested organisms. The absence of non-resistant samples may have influenced the ability of the chemometric methods to accurately categorize durability.