Investigation of the Electrochemical Behavior of CuO-NiO-Co3O4 Nanocomposites for Enhanced Supercapacitor Applications

Author:

Kannan Karthik1ORCID,Chinnaiah Karuppaiya2,Gurushankar Krishnamoorthy23,Krishnamoorthi Raman4ORCID,Chen Yong-Song1ORCID,Murphin Kumar Paskalis Sahaya56ORCID,Li Yuan-Yao56ORCID

Affiliation:

1. Department of Mechanical Engineering, Advanced Institute of Manufacturing with High-Tech Innovations, National Chung Cheng University, Chia-Yi 621301, Taiwan

2. Multifunctional Laboratory, International Research Centre, Kalasalingam Academy of Research and Education, Krishnankoil, Virudhunagar 626126, Tamil Nadu, India

3. Laboratory of Computational Modelling Drugs, Higher Medical and Biological School, South Ural State University, 454080 Chelyabinsk, Russia

4. Pharamaceutics Laboratory, Graduate Institute of National Products, Chang Gung University, Kweishan, Taoyuan 33305, Taiwan

5. Department of Chemical Engineering, National Chung Cheng University, Chia-Yi 621301, Taiwan

6. Advanced Institute of Manufacturing with High-Tech Innovations, National Chung Cheng University, Chia-Yi 621301, Taiwan

Abstract

In the present study, composites incorporating NiO-Co3O4 (NC) and CuO-NiO-Co3O4 (CNC) as active electrode materials were produced through the hydrothermal method and their performance was investigated systematically. The composition, formation, and nanocomposite structure of the fabricated material were characterized by XRD, FTIR, and UV–Vis. The FE-SEM analysis revealed the presence of rod and spherical mixed morphologies. The prepared NC and CNC samples were utilized as supercapacitor electrodes, demonstrating specific capacitances of 262 Fg−1 at a current density of 1 Ag−1. Interestingly, the CNC composite displayed a notable long-term cyclic stability 84.9%, which was observed even after 5000 charge–discharge cycles. The exceptional electrochemical properties observed can be accredited to the harmonious effects of copper oxide addition, the hollow structure, and various metal oxides. This approach holds promise for the development of supercapacitor electrodes. These findings collectively indicate that the hydrothermally synthesized NC and CNC nanocomposites exhibit potential as high-performance electrodes for supercapacitor applications.

Publisher

MDPI AG

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