A New Method for Calculating the Hamaker Constant Based on the Hansen Solubility Parameters for Non-Polar Liquids

Author:

Ohshima Hiroyuki1ORCID,Takeda Shin-ichi2

Affiliation:

1. Faculty of Pharmaceutical Sciences, Tokyo University of Science, Yamazaki 2641, Noda 278-8510, Chiba, Japan

2. Takeda Colloid Techno-Consulting Co., Ltd., Osaka 564-0051, Japan

Abstract

A simple relationship between the Hamaker constant and the Hansen solubility parameters for non-polar liquids is derived by combining a Hamaker constant/surface tension relationship derived by Israelachvili and a Hansen solubility parameters/surface tension relationship derived by Abbott. With this relationship, one can easily estimate the Hamaker constant of non-polar liquids on the basis of the database of the Hansen solubility parameters. This is an entirely new method for calculating the Hamaker constant without recourse to data on the frequency-dependent dielectric permittivity of those substances (which are required for the rigorous Lifshitz theory) and laborious numerical calculations.

Publisher

MDPI AG

Reference17 articles.

1. The London-van der Waals attraction between spherical particles;Hamaker;Physica,1937

2. The theory of molecular attractive forces between Solids;Lifshitz;J. Exper. Theoret. Phys.,1956

3. Israelachvili, J.N. (2011). Intermolecular and Surface Forces, Elsevier. [3rd ed.].

4. The calculation of Hamaker constnats from Lifshitz theory with application to wetting phenomena;Hough;Adv. Colloid Interface Sci.,1980

5. Theory of the stability of strongly charged and of the adhesion of strongly charged particles in solutions of electrolytes;Derjaguin;Acta Physicochim. USSR,1941

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