Nature and Regularities of the Orthorhombic α″-Phase Formation in Binary Titanium Alloys

Author:

Dobromyslov Arkadiy V.1

Affiliation:

1. M.N. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, Yekaterinburg 620108, Russia

Abstract

A systematic study of the phase composition of quenched binary titanium alloys with d-metals of groups 5–11 from periods four to six was carried out using the methods of X-ray diffraction analysis. It was found that the formation of the orthorhombic α″-phase depends on the position of the alloying metal in the periodic table. The formation of the α″-phase occurs only in the systems Ti-V, Ti-Nb, Ti-Mo, Ti-Ru, Ti-Ta, Ti-W, Ti-Re, Ti-Os and Ti-Ir, and in other systems, it does not occur. It was found that the critical parameter for the formation of the α″-phase is the difference in the size of titanium atoms and those of the alloying metal {(rTi − rMe)/rTi 100%}. The formation of the α″-phase occurs only in systems where this value is lower than 9 at.%.

Funder

Ministry of Science and Higher Education of the Russian Federation

”Testing Center of Nanotechnology and Advanced Materials“ Collaborative Access Center

Publisher

MDPI AG

Reference23 articles.

1. Laws of formation of metastable phases in titanium alloys;Bagaryatskii;Dokl. Akad. Nauk SSSR,1958

2. Phase Transformations in Titanium Alloys;Nosova;Metallurgia,1964

3. Collings, E.W. (1984). The Physical Metallurgy of Titanium Alloys, ASM.

4. Zwicker, U. (1974). Titan und Titanlegierungen, Springer.

5. Martensitic transformations in titanium-tantalum alloys;Bywater;Philos. Mag. A,1972

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