The Effect of Chemical and Thermal Treatment for Desizing on the Properties and Chemical Functional Groups of Carbon Fiber

Abstract

In this paper, in order to upcycle carbon fibers (CF), the changes in their mechanical and chemical properties in accordance with time and temperature were investigated, in addition to the oxygen functional group mechanism. When acetone as a chemical desizing agent was used, treatment with acetone for 0.5 h at 60 °C was the optimal condition for the complete removal of the sizing agent, and there was no deterioration in tensile strength. At 25 °C, the carbonyl group (C=O) and hydroxyl group (C-O) declined in comparison to commercial CF, but a novel lactone group (O=C-O) was created. At 60 °C, the oxygen present in the sizing agent was removed and C=O, C-O, and O=C-O decreased. On the contrary, in the case of thermal desizing in an inert gas nitrogen atmosphere, by increasing the temperature, functional groups combining carbon and oxygen were reduced, because nitrogen and oxygen atoms combined with C=O and C-O on the CF surface were eliminated in the form of CO, NO, CO2, NO2, and O2. When desizing via chemical and thermal methods, the amount of functional groups combining carbon and oxygen on the CF surface decreased. Desizing was performed as a pretreatment for surface treatment, so the methods and conditions were different, and related research is insufficient. In this study, we attempted to derive the optimal conditions for desizing treatment by identifying the surface characteristics and mechanisms according to chemical and thermal desizing treatment methods.