Alternative Solid Activators from Waste Glass for One-Part Alkali-Activated Fly Ash/Red Mud Cements

Author:

Marin Nicolaie1,Orbeci Cristina1,Bobiricǎ Liliana1,Rău Ileana2ORCID,Deleanu Calin3ORCID,Bîru Elena Iuliana4,Stănescu Paul Octavian4,Berbecaru Andrei Constantin5,Matei Ecaterina5ORCID,Bobiricǎ Constantin1ORCID

Affiliation:

1. Department of Analytical Chemistry and Environmental Engineering, National University of Science and Technology Politehnica Bucharest, 1-7 Gh. Polizu, 011061 Bucharest, Romania

2. Department of General Chemistry, National University of Science and Technology Politehnica Bucharest, 1-7 Gh. Polizu, 011061 Bucharest, Romania

3. “C.D. Neniţescu”, Institute of Organic and Supramolecular Chemistry, 202-B Spl. Independenţei, 060023 Bucharest, Romania

4. Advanced Polymer Materials Group, National University of Science and Technology Politehnica Bucharest, 1-7 Gh. Polizu Street, 011061 Bucharest, Romania

5. Department of Metallic Materials Processing and Eco-Metallurgy, National University of Science and Technology Politehnica Bucharest, 313 Spl. Independenţei, 060042 Bucharest, Romania

Abstract

Solid activators based on waste glass for the manufacture of one-part alkali-activated fly ash/red mud materials were synthesized, characterized, and tested in this work. The synthesis was carried out via alkaline fusion with sodium hydroxide at different reaction temperatures and at different sodium hydroxide/waste glass mass ratios. The results showed that the reaction temperature decisively influences the properties of the obtained solid activators. Thus, the best results regarding the water solubility of solid activators were obtained for the synthesis temperature of 600 °C, regardless of the sodium hydroxide/waste glass mass ratio. Also, the use of these assortments of solid activators led to obtaining the best compressive strength of one-part alkali-activated fly ash/red mud materials. The best results were obtained for the solid activator synthesized at a temperature of 600 °C and a sodium hydroxide/glass waste mass ratio of two.

Publisher

MDPI AG

Subject

General Materials Science

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