Author:
Sawamura ,Okamoto ,Todokoro
Abstract
Silica-based membranes show both robust properties and high-permeability, offering us great potential for applying them to harsh conditions where conventional organic membranes cannot work. Despite the increasing number of paper and patents of silica-based membranes, their industrial applications have yet to be fully realized, possibly due to their lack of technologies on scaling-up and mass production. In particular, quality of membrane supports decisively impacts final quality of silica-based separation membranes. In this study, therefore, we have developed mass producing technologies of nano-porous supports (φ 12 mm, length 400 mm) with surface center pore size distribution of 1–10 nm, which are generally used as supports for preparing separation membranes with a pore size of less than 1 nm. The developed mass production apparatuses have enabled us to reproducibly produce nano-porous silica-based supports with high permeance (e.g., N2 permeance of more than 10−5 mol m−2 s−1·Pa−1) minimizing effects of membrane defects less than 0.1% of the total flux. The developed nano-porous supports have enabled us to reproducibly produce silica-based separation membranes with high permeace and selectivity (e.g., H2 permeance of about 5 × 10−6 mol m−2 s−1 Pa−1 and H2/SF6 permeance ratio of more than 2000).
Funder
New Energy and Industrial Technology Development Organization
Public Interest Incorporated Foundation KYOTO Industrial Support Organization 21
Subject
Filtration and Separation,Chemical Engineering (miscellaneous),Process Chemistry and Technology
Cited by
4 articles.
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