Influence of Dispersed TiO2 Nanoparticles via Steric Interaction on the Antifouling Performance of PVDF/TiO2 Composite Membranes

Abstract

Herein, the influence of various contents of polyethylene glycol (PEG) on the dispersion of TiO2 nanoparticles and the comprehensive properties of PVDF/TiO2 composite membranes via the steric hindrance interaction was systematically explored. Hydrophilic PEG was employed as a dispersing surfactant of TiO2 nanoparticles in the pre-dispersion process and as a pore-forming additive in the following membrane preparation process. The slight overlap shown in the TEM image and low TSI value (<1) of the composite casting solution indicated the effective dispersion and stabilization under the steric interaction with a PEG content of 6 wt.%. Properties such as the surface pore size, the development of finger-like structures, permeability, hydrophilicity and Zeta potential were obviously enhanced. The improved antifouling performance between the membrane surface and foulants was corroborated by less negative free energy of adhesion (about −42.87 mJ/m2), a higher interaction energy barrier (0.65 KT) and low flux declination during the filtration process. The high critical flux and low fouling rate both in winter and summer as well as the long-term running operation in A/O-MBR firmly supported the elevated antifouling performance, which implies a promising application in the municipal sewage treatment field.