Modeling of Nanofiltration Process Using DSPM-DE Model for Purification of Amine Solution

Abstract

The formation of heat stable salts (HSS) during the natural gas sweetening process by amine solvent causes many problems such as corrosion, foaming, capacity reduction, and amine loss. A modeling study was carried out for the removal of HSS ions from amine solution using nanofiltration (NF) membrane process that ensures the reuse of amine solution for gas sweetening. This model studies the physics of the nanofiltration process by adjusting and investigating pore radius, the effects of membrane charge, and other membrane characteristics. In this paper, the performance of the ternary ions was investigated during the removal process from methyl di-ethanol amine solution by the nanofiltration membrane process. Correlation between feed concentration and permeate concentration, using experimental results with mathematical correlation as Ci,p = f (Ci,f) was used in modeling. The results showed that the calculated data from the model provided a good agreement with experimental results (R2 = 0.90–0.75). Also, the effect of operating conditions (including feed pressure and feed flow rate on ions rejection and recovery ratio across the flat-sheet membrane) was studied. The results showed that the recovery and rejection ratios of the NF membrane depend on the driving pressure across the membrane. While the driving pressure is affected by the feed flow conditions and feed pressure.