Photoelectrocatalytic Reduction of Cr(VI) in Wastewater with a CuBi2O4 Thin Film Photocathode

Abstract

Photoelectrocatalytic approaches show promise for contaminate removal in wastewater through redox reactions. However, the direct treatment of very low concentration heavy metals is a challenging task. Copper bismuth oxide is considered as a potential photocathode material due to its appropriate bandgap width and excellent light absorption properties. In this work, we utilize copper bismuth oxide photoelectrodes with micrometer-scale pores to achieve the efficient and complete reduction of micromolar-level hexavalent chromium(VI) in wastewater. In a continuous 180 min experiment, the reduction rate of 5 µM hexavalent chromium reached 97%, which is an order lower than the drinking standard. Such a process was facilitated by the unique hierarchical microstructure of the oxide thin film and the porous morphology. On the other hand, the structural evolution during the operation was analyzed. A surface passivation was observed, suggesting the possible long-term practical application of this material. This study serves as an important reference for the application of photoelectrocatalysis in addressing Cr(VI) pollution in wastewater, with implications for improving water quality and environmental protection.