Inverse Magnetocaloric Effect in Heusler Ni44.4Mn36.2Sn14.9Cu4.5 Alloy at Low Temperatures

Author:

Kamantsev Alexander P.1ORCID,Koshkid’ko Yuriy S.2ORCID,Gaifullin Ruslan Yu.3ORCID,Musabirov Irek I.3ORCID,Koshelev Anatoliy V.4,Mashirov Alexey V.1,Sokolovskiy Vladimir V.56ORCID,Buchelnikov Vasiliy D.5,Ćwik Jacek2ORCID,Shavrov Vladimir G.1

Affiliation:

1. Kotelnikov Institute of Radioengineering and Electronics of Russian Academy of Sciences, 125009 Moscow, Russia

2. Institute of Low Temperature and Structure Research of Polish Academy of Sciences, 50-422 Wroclaw, Poland

3. Institute for Metals Superplasticity Problems of Russian Academy of Sciences, 450001 Ufa, Russia

4. Institute of Experimental Mineralogy of Russian Academy of Sciences, 142432 Chernogolovka, Russia

5. Department of Condensed Matter Physics, Chelyabinsk State University, 454001 Chelyabinsk, Russia

6. Academic Research Center for Energy Efficiency, National University of Science and Technology “MISIS”, 119049 Moscow, Russia

Abstract

Direct measurements of the magnetocaloric effect were performed in a Heusler Ni44.4Mn36.2Sn14.9Cu4.5 alloy at cryogenic temperatures in magnetic fields up to 10 T. The maximum value of the inverse magnetocaloric effect in a 10 T field was ∆Tad = –2.7 K in the vicinity of the first-order magnetostructural phase transition at T0 = 117 K. Ab initio and Monte Carlo calculations were performed to discuss the effect of Cu doping into a Ni-Mn-Sn compound on the ground-state structural and magnetic properties. It is shown that with increasing Cu content the martensitic transition temperature decreases and the Curie temperature of austenite slightly increases. In general, the calculated transition temperatures and magnetization values correlated well with the experimental ones.

Funder

Russian Science Foundation

Priority-2030 Program of NUST “MISiS”

Ministry of Science and Higher Education of the Russian Federation within the Russian State Assignment

Publisher

MDPI AG

Subject

General Materials Science,Metals and Alloys

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3. Tishin, A.M., and Spichkin, Y.I. (2003). The Magnetocaloric Effect and Its Applications, IOP Publisher.

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