Preparation of MCS from Low-Grade Bauxite Desilication Lye and Adsorption of Heavy Metals

Author:

Chen Cheng1,Chen Chaoyi12,Li Junqi12,Wang Gangan1,Lin Xin1,Ning Deyang1

Affiliation:

1. College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China

2. Guizhou Province Key Laboratory of Metallurgical Engineering and Process Energy Saving, Guiyang 550025, China

Abstract

By utilizing low-grade bauxite desilication solution as raw material and adding lime after thermal reaction, adsorbent MCS was synthesized. X-ray diffraction, Brunauer–Emmett–Teller, Fourier transform infrared spectroscopy, and scanning electron microscopy were used to characterize the MCS, MCS-Pb, and MCS-Cu. The Freundlich model was found to be more suitable for isothermal adsorption, suggesting that the adsorption of Cu2+ and Pb2+ by MCS is not limited to monolayer adsorption. According to the results of the experiment, the maximum adsorption capacities of lead ion and copper ion were found to be Pb2+ (1921.506 mg/g) > Cu2+ (561.885 mg/g), and the adsorption was controlled by chemical reactions following pseudo-second-order kinetics. Electrolyte study results indicated that the presence of background electrolyte did not affect the adsorption of Cu2+ and Pb2+ by MCS.

Funder

National Natural Science Foundation of China

Guizhou Graduate Research Foundation

Guizhou Science and Technology Cooperation Platform

Publisher

MDPI AG

Subject

General Materials Science

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