Effects of Different Calcium Sources on Mechanical Properties of Metakaolin Geopolymers

Author:

Wang Yiren1,Zhang Jiangtao2,Liu Jie3,Fan Deke2,Qu Haiyang2,Zhou Lingzhu1,Zheng Sen4

Affiliation:

1. School of Environment and Civil Engineering, Dongguan University of Technology & Guangdong Provincial Key Laboratory of Intelligent Disaster Prevention and Emergency Technologies for Urban Lifeline Engineering, Dongguan 523808, China

2. China Building Materials Academy, CNBM Zhongyan Technology Co., Ltd., Beijing 100024, China

3. School of Civil Engineering, Sun Yat-sen University, Zhuhai 519082, China

4. ENAC/IIC/LHE, Ecole Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland

Abstract

Metakaolin-based geopolymers have substantial potential as replacements for cement, but their relatively inferior mechanical properties restrict their application. This paper aims to enhance the mechanical properties of metakaolin-based geopolymers by incorporating appropriate amounts of calcium sources. CaCO3, Ca(OH)2, and CaSO4 are three types of calcium sources commonly found in nature and are widely present in various industrial wastes. Thus, the effects of these three calcium sources on the performance of metakaolin-based geopolymers were studied. Through the analysis of the mechanical properties, heat-release behavior during hydration, hydration products, and microstructure of geopolymers, the effectiveness of the aforementioned calcium sources in improving the performance of metakaolin-based geopolymer was evaluated, and the mechanisms of action were elucidated. The results indicate that the pozzolanic reaction between CH and MK could promote MK hydration and increase the proportion of CASH gel in the hydration products, thereby facilitating the setting of the geopolymer and enhancing its strength. CS could react with the active aluminates in MK to form ettringite, thus forming a higher early strength. CC had a lower reactivity with MK and does not improve the performance of MK-based geopolymers.

Funder

National Natural Science Foundation of China

Frontier Exploration Fund of CBMA, Youth Innovative Talent Project of Ordinary University of Guangdong Province

Publisher

MDPI AG

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