Enhanced Raman Scattering in CVD-Grown MoS2/Ag Nanoparticle Hybrids

Author:

Maratos Dionysios M.1,Michail Antonios23,Stamatelatos Alkeos4ORCID,Grammatikopoulos Spyridon45ORCID,Anestopoulos Dimitris3ORCID,Tangoulis Vassilis1ORCID,Papagelis Konstantinos36ORCID,Parthenios John3ORCID,Poulopoulos Panagiotis4ORCID

Affiliation:

1. Department of Chemistry, University of Patras, 26504 Patras, Greece

2. Department of Physics, University of Patras, 26504 Patras, Greece

3. Institute of Chemical Engineering Sciences, Foundation for Research and Technology-Hellas, 26504 Patras, Greece

4. Department of Materials Science, University of Patras, 26504 Patras, Greece

5. Department of Mechanical Engineering, University of Peloponnese, M. Alexandrou 1, 26334 Patras, Greece

6. School of Physics, Department of Solid State Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki, Greece

Abstract

Surface-Enhanced Raman Spectroscopy (SERS) is a powerful, non-destructive technique for enhancing molecular spectra, first discovered in 1974. This study investigates the enhancement of Raman signals from single- and few-layer molybdenum disulfide (MoS2) when interacting with silver nanoparticles. We synthesized a MoS2 membrane primarily consisting of monolayers and bilayers through a wet chemical vapor deposition method using metal salts. The silver nanoparticles were either directly grown on the MoS2 membrane or placed beneath it. Raman measurements revealed a significant increase in signal intensity from the MoS2 membrane on the silver nanoparticles, attributed to localized surface plasmon resonances that facilitate SERS. Our results indicate that dichalcogenide/plasmonic systems have promising applications in the semiconductor industry.

Publisher

MDPI AG

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