Ag-Modified ZnO for Degradation of Oxytetracycline Antibiotic and Reactive Red Azo Dye

Abstract

It is known that low electron-hole separation efficiency is the major disadvantage influencing low photoactivity of the UV-active ZnO photocatalyst. To solve this drawback, the excellent fabrication technique has been used to disperse silver metal on ZnO surface. In this study, an addition of silver content up to 15 wt% was carried out. The 5Ag-ZnO sample, comprising 5 wt% of silver metal, displayed a hexagonal wurtzite structure, and a band gap of 3.00 eV, with high sunlight-active photocatalytic performance of 99–100% and low photo-corrosion problem. The complete degradation of oxytetracycline (OTC) antibiotic and reactive red dye 141 (RR141) dye under natural sunlight was achieved. The highest rate constant of 0.061 min−1 was detected. The enhancement of the performance is mainly due to lowering of the electron-hole recombination rate. Dispersion of silver on ZnO causes the generation of the Schottky barrier at the interface between Ag and ZnO, so that improvement of quantum efficiency and enhancement of the resultant photoactivity could be expected. Furthermore, good distribution of metallic silver also causes a red shift in absorption of light toward the visible spectrum. This is strongly attributed to the surface plasmon resonance effect, which occurred after successful decoration of the noble metal on ZnO. The photocatalyst, with great structural stability, still maintains high photocatalytic efficiency even after five times of use, implying its excellent cycling ability. The present finding offers a new road to generate a silver decorated ZnO photocatalyst for the complete removal of dye and antibiotics contaminated in the environment.